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发表于 18-7-2009 02:35 AM
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原帖由 白羊座aries 于 12-7-2009 06:09 PM 发表 
Which of the following properties decreases when going across the third period from sodium to argon.
1 Density
2 Atomic radius
3 Metallic character
1 density到底是不是decreases when going acro ...
density,rou=m/v
across period,m increase,v decrease(electron packing)
不确定,太久没动chemistry了
[ 本帖最后由 秋分 于 18-7-2009 02:36 AM 编辑 ] |
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发表于 19-7-2009 08:07 PM
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原帖由 秋分 于 18-7-2009 02:35 AM 发表 
density,rou=m/v
across period,m increase,v decrease(electron packing)
不确定,太久没动chemistry了
所以density increase,对吗? |
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发表于 25-7-2009 11:21 AM
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发表于 27-7-2009 10:47 PM
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发表于 28-7-2009 10:37 PM
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原帖由 星星之玲 于 14-2-2009 09:05 PM 发表 
这是physical chemistry 的chapter12 phase equilibrium问题谁能帮我算一下啊?谢谢!
The partition coefficient of a substance X between ether and water is 8.0 .
An aqueous solution containing 5.0g of ...
[X]in ether / [X] in water = 8.0
let x is the amount of X extracted
then (x/100)/(5-x/100) = 8
x = 8(5-x)
9x = 40
x =4.44 |
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发表于 28-7-2009 10:44 PM
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原帖由 星星之玲 于 14-2-2009 09:05 PM 发表 
这是physical chemistry 的chapter12 phase equilibrium问题谁能帮我算一下啊?谢谢!
The partition coefficient of a substance X between ether and water is 8.0 .
An aqueous solution containing 5.0g of ...
[X]in ether / [X] in water = 8.0
let x is the amount of X extracted
then (x/100)/(5-x/100) = 8
x = 8(5-x)
9x = 40
x =4.44 |
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发表于 28-7-2009 11:20 PM
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原帖由 cgcy 于 18-4-2009 12:50 AM 发表 
Mechanism :
NO + F2 -----> NOF + F*
F* + NO -----> NOF
Overall equation:
2NO + F2 -----> 2NOF
Question: Please justify the mechanism in term of reaction kinetics.
Rate = k1[F2][NO]=k-1[NOF][F*]
Rate = k2[F*][NO]=k-2[NOF]
[F*]= k1[F2][NO]/k-1[NOF]
THEN, k2[NO] (k1[F2][NO]/k-1[NOF]) = k-2[NOF]
(k2k1/k-1)[NO]^2[F2]= k-2[NOF]^2
THUS, Rate=K[NO]^2[F2]=K-1[NOF]^2,given that K=(k2k1/k-1) and (K x K-1)=1
correct me if i'm wrong |
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发表于 2-8-2009 12:15 AM
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我这里也有个问题。。
可不可以帮我看我的答案有没有错。。
题目是
SO2 reacts with O2 to produce SO3 which is then used to manufacture H2SO4. A mixture containing SO2 and O2 with a mole of ratio of 2:1, total pressure at beginning 3 atm is passed over V2O5 at 450 degree celcius. The equilibrium partial pressure of SO3 was found to be 1.9atm.
2 SO2 (g) + O2 (g) -----> 2 SO3 (g)
Calculate the equilibrium partial pressure of SO2 and O2.
Determine the equilibrium constant, Kp at 450 degree celcius.
我的答案是 0.1atm 和 0.05atm
Kp 是7220 atm^-1
如果有任何地方做错了。。麻烦指点。。谢谢。。 |
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发表于 3-8-2009 09:23 PM
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想知道
cooridnate bond
dimer
adduct
ligand
是什么分别? |
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发表于 4-8-2009 03:10 PM
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原帖由 bell_25 于 2-8-2009 12:15 AM 发表 
我这里也有个问题。。
可不可以帮我看我的答案有没有错。。
题目是
SO2 reacts with O2 to produce SO3 which is then used to manufacture H2SO4. A mixture containing SO2 and O2 with a mole of ratio of 2:1 ...
2 SO2 (g) + O2 (g) -----> 2 SO3 (g)
initial 2 1 0
final 2(1-0.95) 1-0.95 2(0.95)
= 0.1 =0.05
Kp = (1.90^2)/(0.1^2)(0.05) = 7220 atm^-1
 |
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发表于 7-8-2009 10:59 PM
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回复 302# 白羊座aries 的帖子
我觉得是increase咯
across period, nuclear charge increase, but inner electron no increase, so attraction outer electron to nucleus increase, screening effect decrease, so more compact,so density increase |
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发表于 9-8-2009 11:22 AM
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有谁有STPM Chemistry Experiment 3 的答案。。。
帮帮我。。 |
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发表于 10-8-2009 06:48 PM
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各位,
想问下,inorganic chemistry那本书最好? |
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发表于 23-8-2009 06:10 PM
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如果题目只写: 'when aqueous NaCl undergo electrolysis under standard condition with carbon eletrode, which will be produce at anode ?"
是 Chlorine 还是 Oxygen gas 啊? |
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发表于 24-8-2009 01:09 PM
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发表于 24-8-2009 01:10 PM
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我怎么知道“aqueous"是指”dilute“ 还是 "concentrated" ? |
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发表于 24-8-2009 03:57 PM
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发表于 24-8-2009 04:01 PM
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原帖由 Allison 于 24-8-2009 03:57 PM 发表 
aqueous 就是有水,所以是dilute的
concentrated 也是有水,不是吗? |
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发表于 24-8-2009 04:10 PM
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回复 318# Dicardo 的帖子
erm。。。
如果是concentrated NaCl,那代表Na & Cl ion 比 H2O多
所以Cl ion 会discharged
aqueous 的话, H2O 比较多所以OH ion discharged
你是lower的? |
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发表于 24-8-2009 05:55 PM
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原帖由 Allison 于 24-8-2009 04:10 PM 发表 
erm。。。
如果是concentrated NaCl,那代表Na & Cl ion 比 H2O多
所以Cl ion 会discharged
aqueous 的话, H2O 比较多所以OH ion discharged
你是lower的?
upper 的。。。嘻嘻。。
下星期预考了。。现在才来赶。。。 |
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